| 91年6月19日 08:30 ~ 10:00 化學系 | 誠實是我們珍視的美德， 我們喜愛「拒絕作弊，堅守正直」的你！ |
| 科目： 有機化學和無機化學 |
| PART A：有機化學 | |
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1.
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What is the difference in the structures of poly- trans -isoprene and poly- cis -isoprene? Sketch the arrangements for the two polymers. How do the two differ in their physical properties? |
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2.
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What is the Clemmensen reduction? Give an example. |
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3.
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What is the acyloin reaction? Give an example. |
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4.
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Complete the following reactions. |
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5.
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Complete the following reactions. |
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| PART B：無機化學 | |
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1.
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Give point group for each of the following molecules. (10 %) |
| a. H2O b. CH4 c. PtCl42- d. Mn(CO)5I e. C60 | |
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2.
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Derive the complete character table for the point group C3v. (10 %) |
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3.
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Draw the pictures for the dz2, dx2-y2, dxy,
dxz and dyz atomic orbitals. How do they form 
,  and δ molecular orbitals
in the metal-metal bonded complex ? (10%) |
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4.
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Define the following terms: (a) oxidation addition and reductive elimination |
| (b) associative and dissociative mechanisms (c) trans effect and trans influence | |
| (d) crystal field theory and ligand field theory
(e) high spin and low spin complexes (20%) |
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